Table of Contents
Germanium Alloy Transistors
pictures and a bit of history
- IBM Pictures
- Rick Dill 2008 - e-mails
- Rick Dill 2010 - e-mails
- comments by Robert Garner - Feb 16, 2015
- more dialogs Feb 25, 2015, Germanium PNP Diffused Base in Space Vanguard I Satellite Radio Transmitters
- and more dialogs Feb 26, 2015 - and a family tree :-))
Dear Friends, and others ;-))
Long ago, I (Ed Thelen) read a learned article (way over my head) in either the IRE or AIEE journal, (predecessors to the IEEE of today) proving that the new transistors would never be able to amplify above audio frequencies. Vacuum tubes would always be required for higher frequencies.
Glowing cathodes are here to stay :-))
This has distorted my whole world view. :-(( - Well, sorta ;-))
[Germanium Alloy Transistors were used on the SMS cards used in the 1401 and many early IBM transistor based computers.]
The IBM 083, NPN, alloy junction (equiv 2N1302), used in most of the SMS logic cards. (Thanks to IBM Almaden machine shop for cleanly decapitating.) Words and music on image & below by Rick Dill ;-))
The round germanium die worked for the alloy transistor because it was uniformly doped and didn't matter which side was used for emitter and base. When the diffused base transistors were introduced, the same machine could turn them out with lots of adjustments, but no major re-engineering. The die for the diffused base transistors had a unique shape without mirror symmetry so that the parts could be fed proper side up by the Syntron bowl feeders.
The parts were sonically driven up a long spiral track to the point where they were dispensed to the handler that put the die into the fixture. Notches and other features on the track would derail any die that was upside down of any other anomaly such as a couple of emitter or collector spheres which were stuck together and not free. View of the emitter side. Note the alignment tab, the closest tab on the case base, to aid machine testing and also machine insertion into circuit cards. Very common for this "TO-5" very popular package. TO-5 The IBM 108, PNP, used to drive a 1403 print hammer. Rick Dill adds "This transistor has a "ring" shaped emitter with a base contact inside and outside. In power transistors, most of the current flows right at the edge of the emitter due to base resistance drop as one gets farther from the edge. The ring gives lots of edge with relatively less inactive area. "The collector is probably a circular alloy "dot" which is direct soldered to the can for heat sink purposes. "I am not sure whether this transistor was IBM design of whether it came from Delco or Motorola who were into power transistors for car radios and other potential automotive applications."
Rick Dill 2008 - e-mails
From: Rick Dill < email@example.com > 09/03/2008 10:12 AM To Robert B Garner/Almaden/IBM@IBMUS cc: ... Subject Alloy Transistors Robert, The early 1950's were an interesting time. In the summer of 1951, Bell Labs had a "summer school" for a fair sized group of university professors. The professor who taught optics attended and had lectures from the likes of Shockley and Bardeen as well as some laboratory hands on time. They published a paper with everyone as an author in which they confirmed the Einstein Relationship between drift of electrons and holes under electric field and thermal diffusion. They returned to campus with a small kit of experiments which a fellow student, Jim Boyden and I latched onto and used both for recreation and every opportunity for a project. We were sophomores when we got our hands on this. It included a germanium alloy diode for measuring IV curves, a chip of germanium with rhodium plating on the back (which we had to learn how to replace after etching it off) to be used for making point contact transistors, and a bar of germanium for the Shockley Hall measurement of drift and diffusion of electrons. We fabricated our own point contacts and crude manipulators to put them down near where we wanted them. In the summer of 1954. fresh with a B.S. in physics I had a job at IBM in Poughkeepsie. It was my first industrial research experience and a wonderful experience. Joe Logue was the manager of the small group which included Hannon York, the engineer who invented the current switch circuit (non-saturating), Bob Henle who was a really good circuit guy and lead the company a few years later to abandon core memories and go to semiconductor memories. At the time, the group was just off of the CRT based electrostatic memories used in the 701 and the later mica target CRT-like memories used in the following computers up to the introduction of magnetic cores which were just coming visible in 1954. My assignment was really a gift. Joe wanted higher function circuits with the example being the neon ring counter. As he has told you, with no real hands on experience I was able to postulate that we might be able to produce such a thing with a double-based diode (unijunction transistor) which had multiple emitters and with the help of the small group in the pickle factory actually get a four-state device prototyped. Dick Rutz and John Marinace were the key people in that group and I eventually ended up working for in Rutz's group. I also postulated an adder circuit based upon the Shockley Hall structure, but with deflectors to steer the electron cloud sideways to multiple collectors. We didn't make this, but it did show up a decade later as an academic achievement. While Bell Labs was stuck on point contact transistors (and even made a computer out of them), Joe Logue has recognized the superiority of junction transistors. From a circuit standpoint, the ones available had too much base resistance to work well in digital circuits, although this didn't hamper them for communications. He tried to encourage the vendors to make transistors with low base resistance to little avail since computers were not important to the electronics world at that time. The task got handed to Research where on the fabrication side the team of Rutz and Marinace and their technicians made alloy transistors with a small alloy emitter surrounded by a circular base contact, and a larger collector junction on the back side of the die. Contrary to what most people believed, alloying was a well determined metallurgical process when done right. To do it right, you needed the crystal to have a <111> orientation. This is the slow dissolving direction when subject to dissolution by molten metal, so the sides of the dissolved region were angled along <111> planes and the bottom flat. The depth depended on the volume of the alloy "dot" and the temperature. On cooling, the germanium first cleanly regrew precipitated from the melt and was doped by the materials in the dot (indium gallium for PNP transistors and tin antimony for NPN). The collector on the backside was simply larger and etched more deeply into the germanium chip. The design was IBM's, but we went to TI and contracted with them to manufacture germanium transistors for us. We were allowed only to make 10% of what we needed, which gave us room for special applications such as core drivers or advanced devices before releasing them to TI. In spite of Joe Logue trying to get me to stay and do graduate work in the Syracuse MS program, I went back to Carnegie Tech and moved from physics to EE. 18 months after that Bob Henle visited campus following up on a summer job one of the young faculty had a year after me. IBM wrote three separate contracts. One supported my research with the requirement that I come to Poughkeepsie roughly monthly to report on my progress. The other two supported Dale Critchlow, the young faculty member, and Bob Dennard, one of his students. Both Dale and Bob were working in magnetics at the time. I was the first to join IBM in February 1958 and Critchlow and Dennard joined the following summer. We were all in the same group trying to do circuits with multi-hole magnetics and transistors. I left that project in summer of 1958 to go to Poughkeepsie and work for Dick Rutz with my initial assignment being to duplicate Esaki's work in Japan on tunnel diodes. In 1955, I worked at RCA Labs for the summer on silicon diodes and the observation that they did not behave according to Shockley's theory. There I met Herb Kroemer who is credited (among other things) as the father of the "drift transistor". Kroemer postulated (as a theorist) that a graded impurity doping in the base region would provide a field that greatly speed up transistors. It was only after I got to IBM that I read a patent of Lloyd Hunter which is the patent on the structure, so IBM has at least as much claim as RCA. By diffusing (probably phosphorus) into the germanium blanks, the IBM design became much faster. In 1958 on returning to IBM, I found that the development group had built a fully automated factory for producing alloy transistors. It used syntron sonic driven bowls to feed to germanium die, alloy spheres for emitter and collector, stub leads soldered to the spheres during alloying, and the dished base contact washer. These were fed into high purity carbon fixtures, one for each transistor. Once the assembly was together it went through a hydrogen furnace, after which the transistor was extracted, etched, washed, dried, tested, and then assembled onto a header. The carbon fixture was sent back to be re-used. This room-sized automated factory could product 40 million transistors a year, which was more than IBM needed. We shipped the factory to TI with the stipulation that they could use it only for IBM production for a stated number of years. When the diffused base transistor came in, it was only a small modification to the line to get the die right-side-up so that the diffused surface was facing the emitter. About 1964 I visited TI and saw multiples of this production facility running full tilt to make germanium transistors for the world. Silicon really came in with the system 360. The group that met to work out what would be done was the Compact Committee. I was a research rep on that team. We should talk about that sometime. Bill Harding was one of the key people and I believe that he is still around in Southern CA. What became solid logic technology (SLT) came from his declaration that he could produce individual transistors very cheaply and solder them directly to substrates. This was all an act of faith, but it came to fruition and significantly delayed IBM's serious entry into integrated circuits for logic. When we did get into integrated circuits for logic, electron beam lithography played an immense role in giving IBM a competitive advantage. Hans Pfeiffer was the leader in this technology and is now in Carmel Valley. This is just a little background for ou[r] Thursday discussion. Rick
After the meeting with Rick, Robert Garner wrote
I met with Rick for 3 hours today. He was a PhD summer intern at IBM in 1954, working on multi-emitter Germanium devices. Fascinating conversation on all what was going on a IBM at the time (and later). He thinks he can explain our loopy I-V curves (water contamination causing the usual culprit - surface states.) Finally I have someone to talk to about the physics and manufacturing of our alloy junction transistors. (although I have some old books on topic now too.) He also talked about how hard it was to make the high-voltage core/hammer driver power Ge transistors... - Robert
Rick Dill 2010 - e-mails
On 11/29/2010 12:13 PM, William Donzelli wrote to firstname.lastname@example.org and Robert Garner responded:
>> Have you seen early Philco transistors -- "look a bit like bullets >> - about 1/2 inch long, and maybe 3/16 inch diameter, >> metal with a rounded top" -- on any SMS cards?> A Google image search of 2N501 will show somw Philcos. > >> (I can send higher-res versions of these pics if you need.) > Yes, please. On early transistors, sometimes the distinguishing marks > for each manufacturer are very subtle. > > Thanks! > > -- > Will
From: Rick Dill
Date: Tue, Nov 30, 2010 7:38 pm
Sorry for the late response, but I've been off-line for a couple of days in the Sierra.
Philco had some of the most interesting transistors of the 50's era. There were three families as the technology developed.
All their transistors were made by a very interesting process. They started with the germanium die connected the the base contact ring in an manner essentially identical to the IBM germanium transistors you are used to.
This is then placed between two glass capillaries which served as fluid nozzles for very fine jets of fluid. The two nozzles differed in diameter and diameter of stream with the one on the collector side being larger.
These are used to get two jets of electrolyte impinging on the two exposed sides of the die. The fluid is an electrolyte which contains both indium and gallium in solution. A voltage is applied between the base ring (die) and electrodes in each nozzle. Initially, the polarity used causes electrolytic etching of the germanium, creating relatively smooth flat bottomed indentations from the two sides of the die, with the collector being deeper and wider.
This etching process is monitored by an infrared beam which goes through the fluid and nozzles. When the infrared transmission rises enough, the etch process is stopped and the current reversed. This plates a thin metallic film of indium/gallium (mostly indium) circular film. Leads are attached to these films for the emitter and collector contacts. The resultant transistor is packaged in the "tiny bullets" observed. The base region could be etched down to where it was very thin with an accurately controlled thickness.
The first of these was the "surface barrier" transistor. It used the metal-semiconductor barrier (schottky barrier) for the emitter and collector. This worked OK for the collector, but the emitter wasn't very efficient and the transistors had low current gain compared to competitors. Where they won was on high frequency response.
The next step was to run the finished transistors through a very brief thermal cycle and to slightly "alloy" the emitter and collector films into the germanium. This produced consistent high frequency transistors that were superior to anything on the market. The drawback was that they were fragile because of the very thin membrane base. In the summer of 1954, when I was a summer employee, the circuit team under Joe Logue was investigating these (Jim Walsh, Bob Henle, Jim Mackay, and Hannon Yourke). They ended up rejecting the Philco SBT and Micro-Alloy transistors because of ruggedness concerns.
In 1955, I was at RCA Labs for the summer. My assignment was to look at the forward I/V curves of silicon diodes (which I made). They did not follow Shockley's theory! That was explained a few years later in a classic paper by Shockley, Noyce, and Sah,
A new employee at RCA Labs was Herb Kroemer, just arrived from Germany where he had published a paper on the "drift" or diffused base transistor. Kroemer had correctly worked out the physics which showed that a base region which had an impurity grading from highly doped on the emitter side to low on the collector side would have an internal electric field which would propel minority carriers from the emitter to the collector. RCA immediately put these into manufacturing, as did many including IBM which modified the automated transistor machine to make them.
The actual patent for the graded base structure was actually held by IBM. More on that later!
Philco was quickly able to adapt their process to work with a die which had the base region diffused from one side. They adapted their etching so that the emitter etch depth was very small, while the collector etched deeply into the die. Again, their IR control allowed them precision control of the physical width of the base membrane. This was called the "micro-alloy diffused transistor". Exceedingly good performance for the day, but they continued to be mechanically fragile.
I probably have some philco transistors in my collection. One of these days, I will unearth that and see what is of interest to the computer history museum.
Comments by Robert Garner - Feb 16, 2015
I noticed that the transistor shown in the paper is slightly different from the ones that we use/photographed. Our transistors have a much taller "tab base washer" that embeds the base disk within a circular cavity. This design doesn't look as shock resistant.
This article reports an assembly rate of one transistor every two seconds, but later sources say one per second.
There's one photo of one station of the (remarkable) assembly line. I wish there were some photos of the entire line (likely in TI's archives.)
p.s. I have over 50 scanned and photocopied articles (and several period conference proceedings) on the design and characterization of germanium transistors from the era. No one, including John Bardeen -- who closely investigated them for several years after his Nobel -- really understood fully how germanium transistors worked (i.e., unpredictable behavior and surface effects). Several papers corroborate how transistor production was a black art (i.e., how much atmosphere/humidity to allow into the enclosure, etc). There were conferences on germanium transistors to try to figure them out -- until, that is, silicon came along with it's more robust surface oxide layer. Tongue in cheek, I like to say we'd be living in "German Valley" instead of "Silicon Valley" if germanium had a robust oxide layer like silicon. ;-)
The reason I've been exploring the history of the physics and production of germanium transistors is to gather clues as to why some exhibit memristor-like loopy I-V curves. There are some references to loopy germanium I-V curves, including the very earliest characterization papers on germanium. Do you know any semi-conductor device physicists who could help?
I included this photo of one of our loopy I-V curves in the ISSC 1401 article (strange place for a computer history article), hoping that it might pique someone's interest enough to contact me. No nibbles.
IBM Almaden Research, San Jose, CA
Manager, General Parallel File System (GPFS)
more dialogs Feb 25, 2015
From: Robert Garner
To: Jack Ward transistormuseum
Feb 22, 2015 12:14 am
Subject: Re: IBM Germanium Transistor History and Historic Devices
Thanks for your follow-up, especially on your 077 PNPN germanium thyratron transistor. It would be interesting to characterize. And I wasn't aware of Hunter's patent.*
I haven't taken a part one of the tall case types, but would be willing to donate one of these if you have any interest in case dis-assembly and photos, as you did with the TO-5 case.
Yes, it would be a pleasure to open one up (if there's a "surplus"). Thanks very much for the 1960 Electronics magazine article on the IBM automated assembly system. I have looked for that for a while, and this is very helpful.
If you need a better quality scan, I could secure one at the San Jose (State Univ) library which has the period Electronics magazines in its reference stacks. (I was able to scan its paper on the notched disk storage prototype developed at the NBS in the mid 1950s, studied by the IBM RAMAC developers in San Jose.)
Speaking of characterization, are you aware of (or have observed) the loopy I-V germanium transistor curves I mentioned/showed below?
Here an interesting movie of its tricks (taken by Bill Newman several years ago), with variable trace rates (including low frequencies): http://www.youtube.com/watch?v=9lAvLXQEv2c
* I have a copy of both the 1st (1956) and 2nd edition (1962) of the Handbook of Semiconductor Electronics, edited by Hunter.
The 1st edition contains a "point-contact transistors" section that Joe Logue, in the oral history session (that I recorded at his home), told me that Hunter forced him to include. Joe had strongly felt that, with the development of the higher-yielding alloy-junction transistor, point-contact transistors were becoming obsolete, but some folks, including Hunter, especially given the initial high cost of transistor manufacture, were taken that "only one point-contact transistor was required in order to construct a trigger circuit." Rick Dill first mentioned this (impossible sounding proposition) to me and I didn't believe it until I read the section and saw its I-V curve with a negative slope (akin to a tunnel diode.)
email@example.com wrote: at 5:32 PM
Hello again Robert,
If you'll supply an address, I'll mail you some of the early 1950s/1960s IBM germanium transistors for your research, so you can characterize performance of a variety of these, as well disassemble a "tall-case" unit. Should be very interesting indeed.
I haven't done much in terms of electrical measurement and performance characteristics, although I do have some experience with point contact transistors and other negative resistance devices such as tunnel diodes, unijunction transistors and Shockley diodes. I can provide some of those 1950s devices as well if you are interested. Let me know.
Did you record or transcribe your interview with Joe Logue? I'd be very interested in reviewing this.
PS - I'm traveling on business so it will be couple of weeks before I can mail the transistors.
PPS - I've attached another pdf, this one decribing some historical germanium transistors used in the first U.S. satellites (Explorer I and Vanguard). Not sure if you are interested, but thought the description of germanium transistors in space would be useful.
Robert Garner to Jack firstname.lastname@example.org, at 8:16 PM
Thanks in advance for sending some of the earliest IBM germanium transistors (btw, I also have some) and the "tall case" unit to disassemble/photograph.
I'll pass on the menagerie of negative resistance devices (for now anyway ;-)
Yes, I video recorded my interview of Joe Logue. He was a strong outspoken leader.
I should create a DVD or upload it...
Thanks for the article on the Vanguard transistors.
Looking at the page 4 transistor proto-family tree, it looks like I should properly say that the germanium transistors used in our 1401 are "3rd generation", after the 1st point-contact and after the 2nd "early junction transistor"? (Up to now, I've said that the 1401 used the 2nd type of transistor ever developed.)
On this note, I've wondered why the 1401 didn't use the faster diffused base transistor.
Were they that much more expensive, or perhaps more finicky?
Or why didn't IBM switch to a more reliable silicon transistor?
It's interesting that the transistors used in the 1401 were manufactured late enough to supply 1401s manufactured up until 1972 (and likely beyond for SMS subsystem(s), such as the 2821 used to attach 1403-N1 chain printers to S/360s.)
btw, I have a fairly thick reference book/catalog of all the extant transistor manufacturing firms in the late 1950s (w/ transistor types, specs, etc).
Most of the firms I'd never heard of.
If you don't have it, I'd be happy to loan it out or get a copy made . (I can supply its title tomorrow, as it's at work.)
Rick Dill, cc'd, also gave me a copy of IBM's course materials for their first transistor educational classes, and early Bell Labs instructional manuals.
from Rick Dill to Robert Garner, Feb 25, 2015
I was there at IBM when this all was happening. As a summer student working for Joe Logue in 1954, I saw a lot of his operation, which was much more a circuit based engineering effort looking for what would really work for computer circuits. There I saw the Philco transistors with very thin controlled basewidths first in surface barrier electrodes, then the same with micro-alloy (much better emitters and collectors) and a few years with micro-alloy and diffused base. Logue had two key engineers, Bob Henle and Jim Walsh. All three became early IBM Fellows. The Philco transistors were perhaps a good model with a ring base, but they were mechanically very weak and a little vibration would fracture them. At the time they were the best for switching speed.
The research group in 1954 included a few basic physicists brought to Poughkeepsie from Watson Lab on Columbia campus and a very small and practical group of engineers and chemists including engineer Dick Rutz and chemist John Marinace. In my assignment from Logue to make a functional electronic device like a counter, I got to know both of them in trying to prototype my unijunction counter device that summer and later worked closely with them. It was Rutz who built the prototype devices for what went into the 1401 and beyond. Both Rutz and Marinace were very productive inventors with Rutz concentrating on devices and Marinace on process.
Using point contact-like transistor technology (pnpn .. hook collectors), Rutz invented a point conact-like full adder transistor, which I believe that I have given to the CHM. In 1954, there wasn't really any development activity.
In spite of Logue's trying to convince me to not go to grad school, but stay with him and the Syracuse MS program, I went back to CMU and set up the first lab there that could make transistors with a capital investment of only $1000. That served to build unijunction devices that I used to write the first semiconductor device related thesis in the EE Dept. I was basically without an advisor, but was greatly helped when Henle came to CMU and brought 3 research contracts for myself, Dennard (DRAM) who was then working on magnetics, and Dale Critchlow who had a great career at IBM culminating with deep trench dram chips. My contract required me to go to Poughkeepsie monthly to report on my progress which got me some guidance and lots of access to 650 computers, often sitting with their covers off. My work, while not prominently published was one of the first uses of carrier flow in a semiconductor device. Yes, solving Poisson's equation, numerically. Yes it was 1-D, but it was the first real model for the unijunction transistor.
I came back to IBM after the 3.5 years it took to get my PhD. For about six months I worked on circuits using transistors and multi-aperture cores for logic to get a change and then went back to devices working for Dick Rutz in1958 where I was assigned to build tunnel diodes following up on Esaki's paper. That was great fun starting with germanium and soon moving along with the field to 3/5 compounds like GaAs or GaSb which had direct band-gaps and much higher on to off ratios (and remarkably short life for GaAs which came back a few years later with lasers).
Over those few years, IBM's research had moved to the 701 building which had just opened the summer of 1954 in the heat of summer without air conditioning. The 702 and 703 buildings had been erected and staffed with development engineers and scientists and a number of people from other companies with experience in early semiconductor manufacturing. I got to know many of these well because they were only a building away and, like myself, interested in making things more than basic physics which was the general tenor in the research lab.
In the 703 building (if I remember the number right) were a whole bunch of key people. Bob Slade has been discussed. Mel Klein did a rather amazing job designing a germanium transistor capable of driving core memories. This had to be capable of one amp pulses with a hundred volt against the non-linear inductive swing of the cores. Those were a key component in IBM's early core memory, perhaps more decisive than the cores themselves. Paul Low, later VP of the components division was there and went off to Stanford for a PhD and back. Ed Davis, an underrgrad friend from college came after his PhD at Stanford. He engineered the SLT module technology including the technology for making precision resistors our of screenprinted palladium oxide resistors trimmed to precision resistance with a narrow beam sandblasting. He was also CD president, a little before Paul Low. There was Bill Harding, but I'll come to him later.
Rutz did a good job with the transistor prototyping, more from just building things and paying attention than from design. The 1401 transistor was basically out of his lab. While Herb Kroemer who ended up at RCA is credited with the diffused base (drift) transistor, he is the physicist who first showed it mathematically. The patent for the structure was actually held by Lloyd Hunter who was Logue's boss in the summer of 54 and eventually moved to Stanford and University of Rochester. Years later Hunter taught me and my new bride how to fly gliders.
I was a research rep on the "Compact Committee", a broad range of people looking at the technology for next generation computers. We had system designers logic designers, semiconductor development people, and only a couple of us from research. This went on endlessly with little progress until Bill Harding stood up and declared that he could make a transistor for a nickel in silicon. That turned the whole discussion and became IBM's SLT technology that evolved though discrete transistors to small integrated circuits to modular design of circuits from building blocks. Bipolar was the thrust for performance reasons .. either small fast systems for small computers or full ECL for top end speed like the model 90. Both saturating and ECL were available to the designer.
I wrestled with Bill Harding some years later on process and manufacturing automation. Bill was very senior to me and what came out was an automated factory concept that got implemented in Fishkill for quick turnaround of IC's using electron beam writing for wiring logic chips to get unique chips out quickly. It also ended up somewhat in Burlington for memory chips. My end was developing automated process metrology for in-line measurement. Today's thin film measurement systems, both sprectral and ellipsometric tools derive from what we invented then. It was in that period that I put together a team to understand model and characterize lithography, which was probably the biggest contribution of my career.
Answers to some questions.
Me, I was always restless and moving on. Still worked more across the lines to development than most in research.
- Why didn't the 1401 get diffused base transistors? It was simply a matter of timing. The 1401 was designed when the only transistors available were alloy junctions. Even with them, it took the invention of the current switch circuit (ECL) by Hannon Yourke in 1956 to come of age in the Stretch system later. The diffused base transistors had great advantage in communication initially where the transistor didn't saturate. Once the transistor saturates and charge builds in the base, it has little advantage over an alloy transistor.
- Why didn't IBM use silicon transistors for better reliability? Again it was a matter of timing. At my first visit to TI sometime around 1960, I was shown the making of silicon transistors. These were grown NPN or PNP junctions by changing doping as a crystal was pulled. One then cut rods out of the crystal and probed to find the base. A wire was alloyed to contact the base and contact made at the ends. Expensive and only where you need other charcteristics.
- Silicon Reliability? Until some time after the FET came into use for dynamic logic, and particular for early CMOS, silicon reliability was poorly understood. It was relatively easy to make stable pnp devices, but NPN was really hard. IBM stumbled upon the solution in their SLT which deliberately chose to hand with single devices with precision resistors than IC's. The use on NPN transistors of a phosphorus emitter diffused from a phosphorus doped glass layer deposited over the oxide insulator trapped the mobile sodium that was the bane of reliability in silicon. It wasn't done for reliability but rather to build the device that was wanted. Shortly after the announcement of the 360 a technician was etching the oxide before metallization and caused a shut-down of the line because of leaky transistors, which is how the role of the phosphorus was discovered at IBM.
- Why did IBM got to Texas Instruments for Transistors? This didn't get asked. Everyone in the early transistor business saw analog and communications circuits as the most important thing. Early on that didn't require low base resistance as did logic. This was a prime item for Logue's team. They saw that the IBM circuits were designed for low base resistance. IBM did not really want to get into semiconductor manufacturing early on and the start-up TI was the only company willing to build transistors designed for IBM's needs. The contract built IBM's designs or TI's improvements on them. When the automated transistor making machine was built, it was capable of far more than the 4 million transistors a year IBM had allotted to itself for memory drivers, etc., so the machine, once fully demonstrated, was shipped to Dallas. TI used it only for IBM for the first few years and then replicated it for the vastly growing need for germanium transistors. That machine easily adapted to the diffused base which was a small change from the alloy transistor in terms handling of the parts. The diffused die for the diffused base transistor did have to have a special shape so that it could be rejected from the syntron sonic feeder bowl if it was upside down.
After my work on tunnel diodes and some diversion about the von Neuman scheme for making transistors using majority logic of parametrons (L/C circuits with non-linear diode capacitors). I moved back to GaAs light emitting diodes which physicists generally were excited because of their high efficiency. I got tied up with Nathan et al building devices which the theoreticians thought might be induced to lase. They were right and we published the semiconductor laser the same day as the team at GE. No Bell Labs didn't invent the semiconductor laser even though they claimed so in their 100th anniversry of the telephone publicity. That was great fun because I figured out how to make laser mirrors by crystal cleaving so we quickly had hundreds for any experiment anyone wanted to do. GE was still hand polishing up to just before I published my fabrication technique.
Bored with that and with silicon well established in the development lab, I went back to germanium one more time to see if, as a semiconductor with high mobility for both electrons and holes, we could beat silicon in speed. That was great fun because we ran a silicon project under Dave Dewitt and a germanium under my control, helping each other. Germanium won the switching speed race in 1967, but the physics of germanium suggested a much smaller advantage than my back of the pad start and we exited germanium (to our good credit).
and more dialogs Feb 26, 2015 - and a family tree :-))
From: From: email@example.com - Date: Thu, Feb 26, 2015 4:34 pm
... The attached "Semiconductor Ancestry Tree" might shed some light on this - this is found in a early 1960s WECO handbook "Solid State Devices".
On Thu, Feb 26, 2015 at 7:05 PM, < firstname.lastname@example.org > wrote:
I very much enjoyed your detailed discussion about early IBM transistor development. I have read Bashe et al IBM's Early Computers, which also contains much information about the early IBM transistor work, and your email discussion really adds much to this. I have a couple of questions which I'd like to pose:
Thanks in advance for your comments.
- Did you ever come across or test any of the point contact transistors hand-made at IBM in 1950 by Dickinson's group, as mentioned in Chapter 10 of the Bashe book? These things must be exceedingly rare, with likely few made and fewer still around. As the text reads in the Bashe book, these devices were hand-made using germanium crystals extracted by cracking open 1N48 GE diodes. I'm not sure, but I think this is how most companies got their first experience with making point contact transistors. 1950 is very early in the transistor timeline and I've searched for years for any further info on these IBM devices, so any info or recollections you might have would be much appreciated.
- I'm also very interested in your comments about TI. The relationship with IBM must have taken off very rapidly, and IBM must have been using really large quantities of TI transistors - I'm thinking this because I came across a TI award object (see the attached photo) states that 10,000,000 transistors had been made by TI for IBM by 1960. In my opinion, that's an amazing number! Any thoughts on this?
- Finally, the PNPN or hook transistor you describe must be one of the most unique early semiconductors produced by IBM. I say this because to my knowledge all other commercial PNPN devices were silicon, from such companies as GE, Westinghouse, Shockley and others. It seems that IBM was the lone producer of germanium PNPN transistors. I'm also interested in the early X-4 made by Rutz combined point contact and alloy junctions in a proto thyratron. I've attached a brief writeup on this, and hoping you can add some clarity and historical context. (See attached X-4 writeup). Was this the type of device used in the binary adder you donated to CHM?
From: Rick Dill < email@example.com > - Date: Thu, Feb 26, 2015 9:18 pm
Life is too busy now for me to go search for any artifacts I have, but I appreciate your collecting.
Now to answer your questions on point contact vs pnpn. I haven't read any books,but am looking back in my foggy mind. Hand made point contact transistors are a good point to start. What got me into the field was a summer course Bell Labs had for university faculty in the summer of 1951. The professor who taught optics, Leito, but was better known for his ability as an estimator for costs of brick work, went. Among other things was a joint paper by all of the attendees confirming the correctness of a long ago relationship between drift and diffusion of charged particles by Einstein. The important thing to me and to Jim Boyden, my friend, was the kit he brought home with experiments to use in teaching. Jim and I latched onto it and did one experiment after another whenever we needed a project.
One project was a germanium chip with a rhodium plated back onto which we were supposed to construct "microprobes" to place two point contacts onto the top surface. We found phosphor bronze wire and crudely pointed (I think with angled cutters) and I built some really crude things to get them close together on the surface. [In the process we etched the plating off the back and had to figure out how to replace it] So we made point contact transistor(s) and "formed" the collector with a capacitive discharge and they worked. That would have been about 1952. There were other experiments, like the I/V measurements of a grown p/n junction and a bar of germanium on which we could contact the two ends and inject carriers with one point and detect them with another to show the drift velocity and diffusion. It was part of the independent education of individuals! Jim was last in my view as the technical guy with Paul Allenon the X-Prize. He stayed in physics and I strayed into engineering and devices.
When I got to IBM in 1954 and then back a few years later, there were various views on the point contact. I never heard of the the work of Dickerson, but wouldn't be surprised. IBM was very deeply into germanium, even in the vacuum tube era. While some built computers using vacuum tubes for the logic, IBM early focused on using diodes for logic and vacuum tubes for amplification to the next stage. That meant that the speed depended more on the recovery time of the diodes, which got excess carriers stored if they were on very long, much like saturated transistor circuits. IBM worked on fast recovery diodes with Hughes, who made them for microwave receivers for the military mostly. To get fast recovery, the crystals of germanium were heated up to near melting and mechanically twisted to introduce mechanical defects. While the on/off ratio was reduced, so was the recovery time. These diodes were probably in the IBM 650 series that enabled my phd thesis. They would have been a good source of germanium surfaces which one could put point contacts on, particularly if one were more mechanically sophisticated than we were as undergrads.
When I got to IBM the lore was that the current gain of the point contacts was really that the collector was a np junction from the phosphor in the phosphor bronze contact and the forming process. I can relate to that when we built diffused-alloy transistors later in germanium with an an arsenic doped aluminum alloy emitter into a diffused-base type substrate. With the right crystallographic orientation the alloy penetrated as a v-shaped trench and the arsenic diffused forward in the brief time at about 700C to form the base. The surface diffusion provided the connection to the base contact. With that we achieved raw switching times of 100 picoseconds, but that was in the 1960's with cooperation with TI who was making similar devices for low noise communication apps.
Joe Logue's team simply rejected point contact. The group had been formed after Joe had led the work on the memories for the 701 using surplus radar scope tubes. They had a hard engineering approach. Bell Labs did build a computer with point contacts, but it hardly made a peep in the growing technology.
Dick Rutz' full adder transistor was essentially point contact (i.e. deliberate np collector), and I don't remember exactly how he produced the collector. There were cigar box sized demo units which would add and display .. at very primitive levels.
IBM went to everyone in the industry to get someone who would build low base resistance transistors. That was a characteristic that Logue's circuit guys demanded. No one was interested. The washer shaped base contact was specifically for that purpose. TI, which was just moving up from instrumentation for oil drilling into semiconductors was the only one who stepped up. Everyone else thought that transistors were for communication and that base resistance didn't matter. At that point the group under Rutz had prototyped the transistors, as they did for several generations until IBM made the big change to silicon and SLT. I'm sure that the intitial orders were more modest, but I think that IBM was only allowed to build 4 million transistors a year. 1960 was early in the delivery cycle and the big production had hardly started. IBM also got power devices from Motorola and Delco as well as building some special devices like core memory drivers which needed higher voltage capability than was generally expected from germanium. There were also experiments with transistors made with deposited oxide on germanium .. something we came back to in the mid-1960's as we pushed for speed.
We did lots of things. I tried GaAs transistors after my experience with that material for tunnel diodes. I found it really hard to work with given the primitive technology I had. Still I was ready when the GaAs LED rush came in with the laser following.
Dick Rutz had assembled a small group of key technicians. Ralph McGibbon was ex-navy and steady building devices. Earle Harden was a master toolmaker, put together many of the leading transistors with his fingers, and was a master of precision machining. When I showed up with a new PhD, there was no office available, but a bench in the lab. They taught me as much of the trade as I was capable of learning. How to brace your hands so you could move the tweezers precisely. How to cut a shard of a tiny sphere of indium/gallium and heat it into a smaller sphere on a graphite hot stage for alloying. I learned the hard way to drink less coffee. The day they discovered that I wasn't just another technician was when the site tour guide brought the King of Denmark .. or something like that behind my stool as I was alloying on a hot stage and then introduced me as Dr..... I could see them in the background almost falling off their stools.
Earl Harden went on later ... still a mechanical tech .. to define the lapping process still used in making thin film recording heads, but that is a far different story.